ASYMMETRIC-SYNTHESIS BY ENZYMATIC-HYDROLYSIS OF PROCHIRAL DIENOL DIACETATE

被引：8

作者：

DUHAMEL, P ^{[1
]}

RENOUF, P ^{[1
]}

CAHARD, D ^{[1
]}

YEBGA, A ^{[1
]}

POIRIER, JM ^{[1
]}

机构：

[1] INST RECH CHIM ORGAN FINE,F-76821 MONT ST AIGNAN,FRANCE

来源：

TETRAHEDRON-ASYMMETRY | 1993年 / 4卷 / 12期

关键词：

D O I：

10.1016/S0957-4166(00)82222-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Enzymatic hydrolysis of prochiral dienol diacetate 1 by Candida cylindracea lipase (C C L) leads to the keto enol acetate 2 in high yield with an enantiomeric excess > 98 %. The S configuration of the asymmetric center was assigned.

引用

页码：2447 / 2450

页数：4

共 50 条

[1] ENZYMATIC-HYDROLYSIS OF PROCHIRAL DINITRILES
CROSBY, JA
PARRATT, JS
TURNER, NJ
TETRAHEDRON-ASYMMETRY, 1992, 3 (12) : 1547 - 1550
[2] A NOVEL ENZYMATIC APPROACH TO THE SYNTHESIS OF CHIRAL SULFOXIDES - ENZYMATIC-HYDROLYSIS OF PROCHIRAL SULFINYLDICARBOXYLATES
MIKOLAJCZYK, M
KIELBASINSKI, P
ZURAWINSKI, R
WIECZOREK, MW
BLASZCZYK, J
SYNLETT, 1994, (02) : 127 - 129
[3] ASYMMETRIC ENZYMATIC-HYDROLYSIS OF PROCHIRAL 2-O-ALLYLGLYCEROL ESTER DERIVATIVES
WIRZ, B
SCHMID, R
FORICHER, J
TETRAHEDRON-ASYMMETRY, 1992, 3 (01) : 137 - 142
[4] KINETICS OF A HETEROGENEOUS ENZYMATIC-HYDROLYSIS OF A PROCHIRAL DIESTER
SMITH, GB
BHUPATHY, M
DEZENY, GC
DOUGLAS, AW
LANDER, RJ
JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (16): : 4544 - 4546
[5] SELENOGLUCOSINOLATES - SYNTHESIS AND ENZYMATIC-HYDROLYSIS
KJAER, A
SKRYDSTRUP, T
ACTA CHEMICA SCANDINAVICA SERIES B-ORGANIC CHEMISTRY AND BIOCHEMISTRY, 1987, 41 (01): : 29 - 33
[6] ENANTIOMER-PURE GLYCERIN DERIVATIVES USING THE ENZYMATIC-HYDROLYSIS OF PROCHIRAL ESTERS
KERSCHER, V
KREISER, W
TETRAHEDRON LETTERS, 1987, 28 (05) : 531 - 534
[7] ENZYMATIC-HYDROLYSIS
FOODY, B
PROCEEDINGS - CANPAC 88 : CANADIAN POWER ALCOHOL CONFERENCE: ALCOHOL FUELS FOR TRANSPORTATION, 1988, : 211 - 218
[8] SYNTHESIS OF COPOLYAMIDE-ESTERS AND THEIR ENZYMATIC-HYDROLYSIS
KOMATSU, S
TOKIWA, Y
KOBUNSHI RONBUNSHU, 1993, 50 (10) : 785 - 788
[9] AN ASYMMETRIC-SYNTHESIS OF GLYCEROL DERIVATIVES BY THE ENANTIOSELECTIVE ACYLATION OF PROCHIRAL GLYCEROL
ICHIKAWA, J
ASAMI, M
MUKAIYAMA, T
CHEMISTRY LETTERS, 1984, (06) : 949 - 952
[10] ENZYMATIC-HYDROLYSIS OF PILOCARPINE
ELLIS, PP
LITTLEJOHN, K
DEITRICH, RA
INVESTIGATIVE OPHTHALMOLOGY, 1972, 11 (09): : 747 - +

← 1 2 3 4 5 →