A CONTRIBUTION TO THE CRYSTALLOCHEMISTRY OF BORON-NITRIDE

被引：45

作者：

BROZEK, V

HUBACEK, M

机构：

[1] Department of Inorganic Chemistry, Prague Institute of Chemical Technology

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1992年 / 100卷 / 01期

关键词：

D O I：

10.1016/0022-4596(92)90161-N

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A reaction mechanism of formation and growth of hexagonal boron nitride planar macromoleukules during reductive nitridation of oxidic boron compounds has been proposed. This model was verified by a comparison of computed values of oxygen contents with experimental results and a good agreement has been found. The growth of boron nitride crystallites is suggested to be of a condensation character and the termination of it is seen as a reaction of hydroxyllic and hydrogen radicals in periphery areas of the macromolecules. By this approach an occurrence of a certain amount of oxygen in samples of hexagonal boron nitride treated even at high temperatures can be elucidated. © 1992.

引用

页码：120 / 129

页数：10

共 11 条

[1]

BROZEK V, 1987, CHEM PRUM, V37, P632

[2]

BROZEK V, 1988, CHEM PRUM, V4, P196

[3]

BROZEK V, Patent No. 243889

[4] A NEW ROUTE TO BORON NITRIDE [J].