THE STEREOSELECTIVE REACTION OF SODIUM-CYANIDE WITH THE CATIONIC RUTHENIUM VINYLIDENE COMPLEX [(ETA-5-C5H5)(PME3)2RU=C=C(ME)PH]+

被引：10

作者：

DAVIES, SG

SMALLRIDGE, AJ

机构：

[1] Dyson Perrins Laboratory, Oxford, OX1 3QY, South Parks Road

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 395卷 / 02期

关键词：

D O I：

10.1016/0022-328X(90)85286-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of sodium cyanide with [(η5-C5H5)(PMe3)2RuCC(Me)Ph]PF6 (1) proceeds with high stereoselectivity (> 95 : 5) to give (Z)-(η5-C5H5)(PMe3)2RuC(CN)C(Me)Ph, which under acid conditions isomerises (< 5 : 95) to the E isomer. © 1990.

引用

页码：C39 / C41

页数：3

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