SYNTHESIS AND MOLECULAR-STRUCTURE OF THE FIRST ORGANOMETALLIC NITRIDE CUBANE - [(TI(ETA(5)-C(5)ME(5)))(4)(MU(3)-N)(4)]

被引：49

作者：

GOMEZSAL, P ^{[1
]}

MARTIN, A ^{[1
]}

MENA, M ^{[1
]}

YELAMOS, C ^{[1
]}

机构：

[1] UNIV ALCALA DE HENARES, DEPT QUIM INORGAN, E-28871 MADRID, SPAIN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 21期

关键词：

D O I：

10.1039/C39950002185

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ammonolysis of [Ti(eta(5)-C(5)Me(5))(NMe(2))(3)] at 90 degrees C affords the nitride complex [{Ti(eta(5)-C(5)Me(5))}(4)(mu(3)-N)(4)]; the X-ray crystal structure analysis shows a Ti4N4 core clearly similar to the structural motif of cubic titanium nitride.

引用

页码：2185 / 2186

页数：2

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