SYNTHESIS AND REACTIVITY OF THE FIRST BIS(CROWN ETHER) ENEDIYNE

被引：38
作者：
KONIG, B
RUTTERS, H
机构：
[1] Institut für Organische Chemie der Technischen Universität Braunschweig, D-38106 Braunschweig
来源：
TETRAHEDRON LETTERS | 1994年 / 35卷 / 21期
关键词：
D O I：
10.1016/S0040-4039(00)73220-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The synthesis of a new bis(crown ether)-enediyne 3 via palladium catalyzed coupling reactions is described. On treatment with sodium-hexafluorophosphate two cations are bound by the title compound 3; with potassium ions the sandwich complex 5 is formed. The thermal reactivity of the enediyne moiety towards cyclisation was investigated by differential scanning calorimetry, whereby the metal complexes showed an increased stability.
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页码：3501 / 3504
页数：4
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