CYCLICONDENSATION OF ALKYLACETOACETATES WITH 1,3,5-TRINITROBENZENE AND BASE

被引:0
|
作者
RADHA, N [1 ]
KAMALA, V [1 ]
机构
[1] SEETHALAKSHMI RAMASWAMI COLL, DEPT CHEM, Tiruchirappalli 620002, INDIA
来源
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY | 1995年 / 34卷 / 05期
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中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The condensation reaction between alkylacetoacetate and 1,3,5-trinitrobenzene has been carried out in the presence of triethylamine and diethylamine as the catalysing bases. The reaction kinetics with different alkylacetoacetates is studied and linear steric energy correlation is established. The resultant condensation product has been characterized by elemental analysis, IR, UV/visible and H-1 NMR spectral studies.
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页码:399 / 403
页数:5
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