SYNTHESIS, CHARACTERIZATION AND STRUCTURE OF (N2H5)3MNX5 (X = CL AND BR)

被引：2
|
作者：
KUMAR, NRS [1 ]
NETHAJI, M [1 ]
PATIL, KC [1 ]
机构：
[1] INDIAN INST SCI,DEPT INORGAN & PHYS CHEM,BANGALORE 560012,KARNATAKA,INDIA
来源：
JOURNAL OF COORDINATION CHEMISTRY | 1991年 / 24卷 / 04期
关键词：
HYDRAZINIUM CATION; MANGANESE COMPLEX; X-RAY STRUCTURE;
D O I：
10.1080/00958979109407893
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new hydrazinium complexes of manganese, (N2H5)3MnX5 (X = Cl and Br), have been prepared and characterized by analysis, infrared and visible spectra. The single crystal X-ray structure of the chloride complex has been determined. Only one of the three N2H+ 5cations is coordinated to the metal. In the anion, [Mn(N2H5)Cl5]2−, the coordination polyhedron around the manganese atom is a slightly distorted octahedron. © 1991, Taylor & Francis Group, LLC. All rights reserved.
引用
收藏
页码：333 / 337
页数：5
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