FUNCTIONALIZATION OF SATURATED-HYDROCARBONS .17. REACTIVITY OF CARBON CARBON DOUBLE-BONDS

被引：26

作者：

BARTON, DHR ^{[1
]}

LEE, KW ^{[1
]}

MEHL, W ^{[1
]}

OZBALIK, N ^{[1
]}

ZHANG, L ^{[1
]}

机构：

[1] KOREA RES INST CHEM TECHNOL,CHUNGNAM 305606,SOUTH KOREA

来源：

TETRAHEDRON | 1990年 / 46卷 / 11期

关键词：

D O I：

10.1016/S0040-4020(01)90511-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Gif oxidation systems cleave methylidene olefins into the ketone or aldehyde and formaldehyde. This is considered to be a further manifestation of an Vfe oxenoid species. Similarly, more substituted olefins are oxidized to the corresponding unsaturated ketones or aldehydes. The oxidation of limonene afforded the ketone 24 resulting from methylene cleavage and racemic carvone 25. The latter is considered to originate from a symmetrical π-allyl complex of iron. © 1990.

引用

页码：3753 / 3768

页数：16

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