Equations of state for representing PVT properties and vapor-liquid equilibria of hydrocarbons

被引：0
|
作者：
Solimando, R
Neau, E
Peneloux, A
Rogalski, M
机构：
[1] FAC SCI LUMINY,CHIM PHYS LAB,F-13288 MARSEILLE 9,FRANCE
[2] UNIV METZ,LAB THERMODYNAM & ANAL CHIM,F-57045 METZ 01,FRANCE
来源：
REVUE DE L INSTITUT FRANCAIS DU PETROLE | 1995年 / 50卷 / 06期
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D O I：
暂无
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
A comparative study of several equations of state (EOS) derived from the van der Waals theory was performed. The aim was to select the models able to represent PVT properties of hydrocarbons in large pressure and temperature ranges. 34 hydrocarbons of various sizes and structures were selected. Experimental data of vapor liquid equilibria (vapor pressures and liquid volumes) and PVT properties of compressed fluids were systematically compared with results obtained using selected EOS. It was shown that only the complex EOS (especially the COR equation) are able to represent volumetric properties in wide temperature and presssure ranges, the critical region included.
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页码：791 / 805
页数：15
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