POLYMERIZATION OF METHYL-METHACRYLATE INDUCED BY MICELLAR SOLUTION OF CATIONIC SURFACTANTS

被引：1
|
作者：
AOKI, S
NAKAMAE, S
机构：
来源：
JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY | 1994年 / A31卷 / 05期
关键词：
D O I：
10.1080/10601329408545330
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The polymerization of methyl methacrylate was induced by a micellar solution of cationic surfactants, such as benzyldimethylphenylammonium chloride, dodecyltrimethylammonium chloride, and cetyltrimethylammonium chloride, in the absence of added initiator to yield a high molecular weight polymer at 60-80-degrees-C. The initiation mechanism was compared with other spontaneous polymerization systems. The monomer-solubilized micelle as the reaction locus was emphasized to facilitate the production of the initiating radical species.
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页码：573 / 579
页数：7
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