THE ROTATIONAL SPECTRUM OF THE FLUOROBENZENE-ARGON VAN-DER-WAALS COMPLEX

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作者：

STAHL, W

GRABOW, JU

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ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES | 1992年 / 47卷 / 05期

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O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The rotational spectrum of the fluorobenzene-argon complex has been studied in the microwave region between 7 and 18 GHz. using a pulsed molecular beam microwave Fourier transform spectrometer. The rotational constants were found to be A=1811.81369(11) MHz, B=1105.12965(15) MHz, C=901.84281(5) MHz, the centrifugal distortion constants are DELTA(J)=2.6886(17) kHz, DEKTA(JK)= 8.3761(52) kHz, DELTA(K)=-8.278(5) kHz, delta(J)=0.65993(72) kHz, and delta(K)=6.013(11)kHz. The argon atom is placed 3.55 angstrom above the ring plane.

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页码：681 / 684

页数：4

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共 13 条

[1] AN AUTOMATIC MOLECULAR-BEAM MICROWAVE FOURIER-TRANSFORM SPECTROMETER [J].

ANDERSEN, U ;

DREIZLER, H ;

GRABOW, JU ;

STAHL, W .

REVIEW OF SCIENTIFIC INSTRUMENTS, 1990, 61 (12) :3694-3699

[2] STRETCH BEND COUPLING BETWEEN VANDERWAALS MODES IN THE S1 STATE OF SUBSTITUTED BENZENE-AR1 COMPLEXES [J].

BIESKE, EJ ;

RAINBIRD, MW ;

ATKINSON, IM ;

KNIGHT, AEW .

JOURNAL OF CHEMICAL PHYSICS, 1989, 91 (02) :752-761

[3] ROTATIONAL SPECTRUM AND DIPOLE-MOMENT OF THE BENZENE-ARGON VANDERWAALS COMPLEX [J].

BRUPBACHER, T ;

BAUDER, A .

CHEMICAL PHYSICS LETTERS, 1990, 173 (5-6) :435-438

[4] MICROWAVE SPECTRUM AND ELECTRIC DIPOLE MOMENT OF FLUOROBENZENE [J].

DEKOWALEWSKI, DG ;

KOKERITZ, P ;

SELEN, H .

JOURNAL OF CHEMICAL PHYSICS, 1959, 31 (05) :1438-1438

[5] RO GEOMETRIES OF FLUOROBENZENES AND DISTORTIONS IN BENZENE-RING STRUCTURE ON SUBSTITUTION [J].

DORAISWAMY, S ;

SHARMA, SD .

JOURNAL OF MOLECULAR STRUCTURE, 1983, 102 (1-2) :81-92

[6] INTERDEPENDENCE OF PARAMETERS IN SPECTROSCOPIC DATA REDUCTION [J].

FEMENIAS, JL .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1990, 144 (01) :212-223

[7] 2-COLOR PHOTOIONIZATION OF VANDERWAALS COMPLEXES OF FLUOROBENZENE IN A SUPERSONIC FREE JET [J].

GONOHE, N ;

SHIMIZU, A ;

ABE, H ;

MIKAMI, N ;

ITO, M .

CHEMICAL PHYSICS LETTERS, 1984, 107 (01) :22-26

[8] 2-COLOR PHOTOIONIZATION OF VANDERWAALS COMPLEXES OF FLUOROBENZENE AND HYDROGEN-BONDED COMPLEXES OF PHENOL IN SUPERSONIC JETS [J].

GONOHE, N ;

ABE, H ;

MIKAMI, N ;

ITO, M .

JOURNAL OF PHYSICAL CHEMISTRY, 1985, 89 (17) :3642-3648

[9] INTERDEPENDENCE OF PARAMETERS IN MULTIVARIATE FITS [J].

GRABOW, JU ;

HEINEKING, N ;

STAHL, W .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1992, 152 (01) :168-173

[10] A PULSED MOLECULAR-BEAM MICROWAVE FOURIER-TRANSFORM SPECTROMETER WITH PARALLEL MOLECULAR-BEAM AND RESONATOR AXES [J].

GRABOW, JU ;

STAHL, W .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 1990, 45 (08) :1043-1044