CHEMICAL LITHIUM INSERTION TO POTASSIUM MOLYBDENUM BRONZE

被引：2

作者：

SENOH, T

UENO, S

MIURA, T

KISHI, T

机构：

来源：

DENKI KAGAKU | 1993年 / 61卷 / 05期

关键词：

CHEMICAL LITHIATION; MOLYBDENUM BRONZE; K0.30MOO3;

D O I：

10.5796/electrochemistry.61.561

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The chemical lithium insertion to K0.30MoO3 powder was investigated in nitrogen atmosphere. Changes in X-ray diffraction patterns, the dependence of the open-circuit potential on x = (Li/Mo) ratio and other electrochemical data showed that chemical lithiation of K0.30MoO3 occurred in three different composition regions and that thermodynamic properties of LixK0.30MoO3 were controlled by structural changes derived from interaction of lithium ions in host matrix. Especially, the solid solution of Li-K0.30MoO3 existed as a single phase within a stoichiometric range of 0<x<0.35.

引用

页码：561 / 564

页数：4

共 7 条

[1] ELECTROCHEMICAL AND CHEMICAL INSERTION EXTRACTION OF LITHIUM INTO FROM POTASSIUM MOLYBDENUM BRONZE
SENOH, T
SAKURAI, T
MIURA, T
KISHI, T
DENKI KAGAKU, 1994, 62 (09): : 836 - 839
[2] SODIUM INSERTION TO POTASSIUM MOLYBDENUM BRONZE
SENOH, T
SAWAMOTO, M
MIURA, T
KISHI, T
DENKI KAGAKU, 1993, 61 (12): : 1342 - 1346
[3] Band structure of the quasi two-dimensional purple molybdenum bronze
Guyot, H.
Balaska, H.
Perrier, P.
Marcus, J.
SURFACE SCIENCE, 2006, 600 (18) : 3860 - 3864
[4] Calcium Molybdenum Bronze as a Stable High-Capacity Cathode Material for Calcium-Ion Batteries
Chae, Munseok S.
Kwak, Hunho H.
Hong, Seung-Tae
ACS APPLIED ENERGY MATERIALS, 2020, 3 (06): : 5107 - 5112
[5] Hydrothermal synthesis and structure determination of a novel hexagonal ammonium molybdenum bronze, NH4Mo6O18
Jiang, CC
Liu, G
Wei, YG
Wang, W
Zhang, SW
INORGANIC CHEMISTRY COMMUNICATIONS, 1999, 2 (06) : 258 - 260
[6] THERMAL-DECOMPOSITION OF HYDROGEN MOLYBDENUM BRONZE, H0.25MOO3, IN A NITROGEN ATMOSPHERE - DEFECTS AND PHASE-TRANSFORMATIONS
EDA, K
JOURNAL OF MATERIALS CHEMISTRY, 1992, 2 (05) : 533 - 538
[7] Lithium insertion properties of LixTiNb2O7 investigated by neutron diffraction and first-principles modelling
Catti, Michele
Pinus, Ilya
Knight, Kevin
JOURNAL OF SOLID STATE CHEMISTRY, 2015, 229 : 19 - 25

← 1 →