ASYMMETRIC ALDOL REACTIONS OF CHIRAL IMIDAZOLIDINONE FISCHER CARBENE COMPLEXES

被引：45
|
作者：
POWERS, TS
SHI, Y
WILSON, KJ
WULFF, WD
RHEINGOLD, AL
机构：
[1] UNIV CHICAGO,DEPT CHEM,SEARLE CHEM LAB,CHICAGO,IL 60637
[2] UNIV DELAWARE,DEPT CHEM,NEWARK,DE 19716
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 23期
关键词：
D O I：
10.1021/jo00102a003
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Highly selective aldol reactions with a-unsubstituted enolates are described for a new class of chiral carbene complexes derived from chiral imidazolidinones in which the position of the chiral center is specifically defined by the chelation of the chiral auxilliary to the metal center.
引用
收藏
页码：6882 / 6884
页数：3
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