MICELLAR HEADGROUP SIZE AND ANION NUCLEOPHILICITY IN SN2 REACTIONS

被引：73

作者：

BONAN, C

GERMANI, R

PONTI, PP

SAVELLI, G

CERICHELLI, G

BACALOGLU, R

BUNTON, CA

机构：

[1] UNIV AQUILA,DIPARTIMENTO CHIM INGN CHIM & MAT,I-64100 LAQUILA,ITALY

[2] UNIV ROME LA SAPIENZA,CNR,CTR SUI MECC REAZ,DIPARTIMENTO CHIM,I-00185 ROME,ITALY

[3] UNIV CALIF SANTA BARBARA,DEPT CHEM,SANTA BARBARA,CA 93106

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1990年 / 94卷 / 13期

关键词：

D O I：

10.1021/j100376a031

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Rates of reaction of OH- with methyl naphthalene-2-sulfonate (MeONs) in aqueous cationic surfactants (C16H33NR3OH, R = Me, Et, n-Pr, n-Bu, and cetylquinuclidinium hydroxide) increase with increasing surfactant and hydroxide ion concentrations. The variations of rate constants can be fitted to an equation that describes the distribution of both reactants between water and micelles in terms of Langmuir isotherms. The Langmuir coefficients for OH- decrease in the head-group sequence Me3N > quinuclidinium > Et3N > Pr3N > Bu3N. The second-order rate constants at the micellar surfaces are not very sensitive to the bulk of the head group, although they increase at high added OH-. Rate constants for attack of water on micellar-bound substrate increase with increasing bulk of the head group. © 1990 American Chemical Society.

引用

页码：5331 / 5336

页数：6

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