FUNCTIONAL TETRAHEDRAL ZINC-COMPLEXES

被引：63
|
作者：
ALSFASSER, R [1 ]
POWELL, AK [1 ]
VAHRENKAMP, H [1 ]
机构：
[1] UNIV FREIBURG,INST ANORGAN & ANALYT CHEM,ALBERTSTR 21,W-7800 FREIBURG,GERMANY
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 08期
关键词：
D O I：
10.1002/anie.199008981
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A hydrophobic pocket is formed by the residues R(Ph, tBu) in the zinc compounds L3Zn–X 1, X = NO 3⊖, CH 3⊖ and C2H5S⊖. The first unequivocally characterized hydroxocomplex of zinc [L3ZnOHZnL3](ClO4)3, L = tert‐butylpyrazole anion, was formed by hydrolysis, presumably via the intermediate cation with X = H2O. In the four complexes the whole hard/soft scale is covered with respect to the ligand X. There are structural relationships to the active centers of zinc‐containing enzymes. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany
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页码：898 / 899
页数：2
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