POLYCYCLIC CHROMANS VIA NOVEL TRICYCLIC-2-PHENYL-4H-1,3,2-BENZODIOXABORINS

被引：7

作者：

BISSADA, S ^{[1
]}

LAU, CK ^{[1
]}

BERNSTEIN, MA ^{[1
]}

DUFRESNE, C ^{[1
]}

机构：

[1] MERCK FROSST CTR THERAPEUT RES,POINTE CLAIRE H9R 4P8,PQ,CANADA

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 22期

关键词：

D O I：

10.1016/S0040-4039(00)73073-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This paper describes a straightforward synthesis of complex polycyclic chromans. They are prepared from novel tricyclic-2-phenyl-4H-1,3,2-benzodioxaborins via a bicyclic orthoquinone-methide intermediate generated in situ under thermolysis or Lewis acid condition. The dioxaborins react with various allyl trimethylsilanes or with ethyl vinyl ether to give polycyclic chromans after acid cyclization or directly.

引用

页码：3691 / 3694

页数：4

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