METAL-ASSISTED ORGANIZATION RATHER THAN PREORGANIZATION FOR THE DESIGN OF MACROCYCLIC HOSTS

被引：39

作者：

KOBUKE, Y ^{[1
]}

SUMIDA, Y ^{[1
]}

HAYASHI, M ^{[1
]}

OGOSHI, H ^{[1
]}

机构：

[1] KYOTO UNIV,FAC ENGN,DEPT SYNTHET CHEM,KYOTO 606,JAPAN

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 11期

关键词：

D O I：

10.1002/anie.199114961

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Boric acid initiates the formation of coronand 1 from 2, providing the framework necessary for the strong complexation of alkali metal ions. This approach to the synthesis of the macrocyclic host allows a greater flexibility than the standard preorganization method. A bicyclic coronand is also obtained by this strategy. M = K, Na.

引用

页码：1496 / 1498

页数：3

共 24 条

[1]

[Anonymous], 1981, ANGEW CHEM, V93, P584

[2]

[Anonymous], 2010, J AM CHEM SOC, DOI DOI 10.1021/ja102148f

[3] PREORGANIZATION - FROM SOLVENTS TO SPHERANDS [J].