APPARENT RATE-CONSTANT FOR DIFFUSION-CONTROLLED 3-MOLECULE REACTIONS

被引:16
作者
BURLATSKY, SF [1 ]
MOREAU, M [1 ]
机构
[1] RUSSIAN ACAD SCI,INST CHEM PHYS,MOSCOW 117977,RUSSIA
来源
PHYSICAL REVIEW E | 1995年 / 51卷 / 03期
关键词
D O I
10.1103/PhysRevE.51.2363
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
We present simple explicit estimates for the apparent reaction rate constant for three-molecule reactions. For diluted systems and d>1, it depends only on the diffusion coefficients and sizes of the reacting particles. For small concentrations and d≤1, it is also time dependent. For concentrated systems, it gains the dependence on concentrations. © 1995 The American Physical Society.
引用
收藏
页码:2363 / 2367
页数:5
相关论文
共 22 条
[1]  
BALAGUROV BY, 1974, ZH EKSP TEOR FIZ, V38, P968
[2]   DIFFUSION-LIMITED 3-BODY REACTIONS IN ONE-DIMENSION [J].
BENAVRAHAM, D .
PHYSICAL REVIEW LETTERS, 1993, 71 (22) :3733-3735
[3]  
BURLATSKY S, 1980, SOV J PHYS CHEM, V54, P1741
[4]  
BURLATSKY S, 1978, THESIS I CHEM PHYSIC
[5]  
BURLATSKY S, 1989, THESIS I CHEM PHYSIC
[6]  
BURLATSKY SF, 1978, TEOR EKSP KHIM, V14, P343
[7]  
COMPTON RG, 1991, KINETIC MODELS CATAL, V32
[10]   A STOCHASTIC-THEORY OF CHEMICAL-REACTION RATES .2. APPLICATIONS [J].
GAVEAU, B ;
HYNES, JT ;
KAPRAL, R ;
MOREAU, M .
JOURNAL OF STATISTICAL PHYSICS, 1989, 56 (5-6) :895-910