Solidification/stabilization of toxic metal wastes using coke and coal combustion by-products

被引:29
作者
Vempati, RK [1 ]
Mollah, MYA [1 ]
Chinthala, AK [1 ]
Cocke, DL [1 ]
Beeghly, JH [1 ]
机构
[1] DRAVO LIME,PITTSBURGH,PA 15225
关键词
D O I
10.1016/0956-053X(95)00050-A
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
A study has been conducted to evaluate the potential of a special scrubber waste, NISCO Cyclone Ash (NCA), which contains substantial calcium oxide and calcium sulfites/sulfates for solidification/stabilization (S/S) of toxic metal wastes. The mineralogical compositions of the NCA and a class ''C'' fly ash have been characterized by X-ray diffraction (XRD). Hydrated mixtures of these wastes have been examined by XRD and found to form ettringite. Low concentrations of As (15 mu g ml(-1)), Ba (500 mu g ml(-1)), Cr (15 mu g ml(-1)), Pb (15 mu g ml(-1)), and Zn (1000 mu g ml(-1)) were added to these hydrated mixtures and found to be successfully immobilized and solidified, as determined by the Toxicity Characteristic Leaching Procedure (TCLP). In addition, the mineralogy, chemistry and leaching characteristics of these combined waste products and their interactions with toxic metals are discussed.
引用
收藏
页码:433 / 440
页数:8
相关论文
共 29 条
[1]  
Barth EF., 1990, STABILIZATION SOLIDI
[2]  
BUTLER LG, 1992, CHEM MICROSTRUCTURE, P151
[3]   A MODEL FOR LEAD RETARDATION OF CEMENT SETTING [J].
COCKE, D ;
ORTEGO, JD ;
MCWHINNEY, H ;
LEE, K ;
SHUKLA, S .
CEMENT AND CONCRETE RESEARCH, 1989, 19 (01) :156-159
[4]   THE BINDING CHEMISTRY AND LEACHING MECHANISMS OF HAZARDOUS SUBSTANCES IN CEMENTITIOUS SOLIDIFICATION STABILIZATION SYSTEMS [J].
COCKE, DL .
JOURNAL OF HAZARDOUS MATERIALS, 1990, 24 (2-3) :231-253
[5]   AN XPS AND EDS INVESTIGATION OF PORTLAND-CEMENT DOPED WITH PB-2+ AND CR-3+ CATIONS [J].
COCKE, DL ;
MCWHINNEY, HG ;
DUFNER, DC ;
HORRELL, B ;
ORTEGO, JD .
HAZARDOUS WASTE & HAZARDOUS MATERIALS, 1989, 6 (03) :251-267
[6]   AN XPS AND SEM/EDS CHARACTERIZATION OF LEACHING EFFECTS ON LEAD-DOPED AND ZINC-DOPED PORTLAND-CEMENT [J].
COCKE, DL ;
MOLLAH, MYA ;
PARGA, JR ;
HESS, TR ;
ORTEGO, JD .
JOURNAL OF HAZARDOUS MATERIALS, 1992, 30 (01) :83-95
[7]  
Cocke DL, 1992, CHEM MICROSTRUCTURE, P187
[8]  
Conner JR., 1990, CHEM FIXATION SOLIDI
[9]  
Cote P., 1989, ENV ASPECTS STABILIZ
[10]  
DAVIS RC, 1991, P 5 INT S CER NUCL H