SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF OXOTRIMESITYLIRIDIUM(V)

被引：118

作者：

HAYMOTHERWELL, RS

WILKINSON, G

HUSSAINBATES, B

HURSTHOUSE, MB

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,JOHNSON MATTHEY LAB,LONDON SW7 2AY,ENGLAND

[2] UNIV WALES CARDIFF,DEPT CHEM & APPL CHEM,CARDIFF CF1 3TB,WALES

来源：

POLYHEDRON | 1993年 / 12卷 / 16期

关键词：

D O I：

10.1016/S0277-5387(00)81474-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The interaction of trimesityliridium(III) with trimethylamine oxide gives quantitative yields of the green iridium(V) complex Ir(O)(mes)3, whose X-ray crystal structure has been determined. The oxo compound is also obtained by interaction of dioxygen with Ir(mes)3 and Ir(mes)4. A similar oxo species has also been obtained from Ir(2,6-Me2C6H3)4. The molecular structure of Ir(O)(mes)3 is distorted tetrahedral with Ir=O and Ir-C bond lengths of 1.725(9) and 1.989-2.034(13) angstrom, respectively.

引用

页码：2009 / 2012

页数：4

共 10 条

[1] OXIDATION OF HEXAAQUAIRIDIUM(III) AND RELATED STUDIES - PREPARATION AND PROPERTIES OF IRIDIUM(III), IRIDIUM(IV), AND IRIDIUM(V) DIMERS AS AQUA IONS
CASTILLOBLUM, SE
RICHENS, DT
SYKES, AG
[J]. INORGANIC CHEMISTRY, 1989, 28 (05) : 954 - 960
[2] COTTON FA, 1988, ADV INORG CHEM RAD, P916
[3] SOME REACTIONS OF TETRAKIS (TERT-BUTYLIMIDO) OSMIUM (VIII) - X-RAY CRYSTAL-STRUCTURES OF OS(NBUT)O(O2CBUT)2(NH2BUT)2.BUTCO2H, (BUTN)2OS(MU-NBUT)2OS(NBUT)X2 (X = CL OR I) AND [OS2(NBUT)4(MU-NBUT)2]I3
DANOPOULOS, AA
WILKINSON, G
HUSSAINBATES, B
HURSTHOUSE, MB
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (08): : 1855 - 1860
[4] SYNTHESIS AND STRUCTURE OF IRIDIUM TETRAMESITYL
HAYMOTHERWELL, RS
WILKINSON, G
HUSSAINBATES, B
HURSTHOUSE, MB
[J]. POLYHEDRON, 1991, 10 (12) : 1457 - 1458
[5] HOMOLEPTIC MESITYLS OF IRIDIUM(III,IV,V) AND RUTHENIUM(IV,V)
HAYMOTHERWELL, RS
WILKINSON, G
HUSSAINBATES, B
HURSTHOUSE, MB
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (24): : 3477 - 3482
[6] HOMOGENEOUS CATALYSIS OF SILANE ALCOHOLYSIS VIA NUCLEOPHILIC-ATTACK BY THE ALCOHOL ON AN IR(ETA-2-HSIR3) INTERMEDIATE CATALYZED BY [IRH2S2(PPH3)2]SBF6 (S=SOLVENT)
LUO, XL
CRABTREE, RH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (07) : 2527 - 2535
[7] STAVROPOULOS P, 1978, J CHEM SOC DA, P557
[8] STAVROPOULOS P, 1987, J CHEM SOC DA, P169
[9] TANKE RS, 1991, ORGANOMETALLICS, V10, P615
[10] AN EMPIRICAL-METHOD FOR CORRECTING DIFFRACTOMETER DATA FOR ABSORPTION EFFECTS
WALKER, N
STUART, D
[J]. ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (JAN): : 158 - 166

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