Ion-molecular interactions in the HCl-isopropanol system

被引：2
|
作者：
Burdin, VV [1 ]
Voloshchenko, GI [1 ]
Maiorov, VD [1 ]
Librovich, NB [1 ]
机构：
[1] RUSSIAN ACAD SCI,NN SEMENOV CHEM PHYS INST,MOSCOW 117977,RUSSIA
来源：
RUSSIAN CHEMICAL BULLETIN | 1995年 / 44卷 / 09期
关键词：
IR spectra; hydrogen bond; hydrogen chloride; isopropanol; solutions;
D O I：
10.1007/BF01151291
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Multiple Attenuated Total Reflectance (MATR) IR spectra of solutions of HCl in isopropanol, containing 0 to 43 mol. % HCl, were studied in the 900-4000 cm(-1) range. The addition of HCl to (PrOH)-O-i yields proton disolvates (C3H7OH...H...OHC3H7)(+) with strong symmetrical H-bonds. At high concentrations of HCl (C-HCl(0) > 5.7 mol L(-1), C-PriOH(0)/C-HCl(0) < 2), when the number of alcohol molecules is not enough to form disolvates with all of the protons present in the solution, (Cl...H...Cl)(-) ions are formed, in addition to (C3H7OHH+. The spectra of these ions have been assigned.
引用
收藏
页码：1684 / 1687
页数：4
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