EFFICIENT CATALYTIC ADDITION OF AROMATIC CARBON-HYDROGEN BONDS TO OLEFINS

被引：1214

作者：

MURAI, S

KAKIUCHI, F

SEKINE, S

TANAKA, Y

KAMATANI, A

SONODA, M

CHATANI, N

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita

来源：

NATURE | 1993年 / 366卷 / 6455期

关键词：

D O I：

10.1038/366529a0

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

The selective cleavage of carbon-hydrogen bonds in organic compounds is a critical step in many organic syntheses, and is particularly important in the conversion of hydrocarbons to useful organic compounds. An organometallic ruthenium complex can cleave C-H bonds in a variety of aromatic systems, leading to addition to alkenes by C-C bond formation. The catalyst operates with a degree of efficiency, selectivity and generality that will make it extremely valuable in organic synthesis.

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页码：529 / 531

页数：3

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