SYNTHESIS, BINDING-PROPERTIES AND SELF-FUNCTIONALIZATION OF A STEROID-CAPPED PORPHYRIN

被引：57

作者：

BONARLAW, RP

SANDERS, JKM

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 08期

关键词：

D O I：

10.1039/c39910000574

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A porphyrin capped with a steroidal superstructure bearing convergent hydroxy groups has been synthesized and shown to bind a variety of functionalized amines via a combination of metal-amine and hydrogen-bonding interactions; the metal-ligand interaction was used to catalyse and control selective acylation of a single hydroxy group in the cap.

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页码：574 / 577

页数：4

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