A NEW STRUCTURE OF OXOVANADATES MV2O6-NIV2O6

被引：15

作者：

MULLERBUSCHBAUM, H

KOBEL, M

机构：

[1] Inst. f. Anorg. Chemie d. Univ., Kiel, W‐2300

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1991年 / 596卷 / 05期

关键词：

NICKEL; VANADIUM; OXIDE; CRYSTAL STRUCTURE;

D O I：

10.1002/zaac.19915960104

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Single crystals of NiV2O6 were prepared by solid state reactions below the melting point of the compound. It crystallizes with triclinic symmetry, space group C(i)1 - P1BAR; a = 7.128; b = 8.820; c = 4.793 angstrom; alpha = 90.24; beta = 94.10; gamma = 102.15-degrees; Z = 3. Ni2+ and two of the three vanadium point positions show an octahedral surrounding by O2-ions. The third V5+ position is tetrahedrally coordinated. The crystal structure will be shown and discussed.

引用

页码：23 / 28

页数：6

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