FROM BUTADIYNYL (-C-C-C-CR) LIGANDS TO ALKYLIDYNE-CARBIDES - SYNTHESIS AND CHARACTERIZATION OF THE UNUSUAL HEXANUCLEAR RUTHENIUM CARBIDO CLUSTERS [RU-6(CO)(13)(MU-CO)(2)(MU-PPH(2))(MU-5-C)(MU(3)-C-C-CR)] (R=BU(T), PH)

被引：27

作者：

BLENKIRON, P ^{[1
]}

TAYLOR, NJ ^{[1
]}

CARTY, AJ ^{[1
]}

机构：

[1] UNIV WATERLOO,DEPT CHEM,GUELPH WATERLOO CTR GRAD WORK CHEM,WATERLOO,ON N2L 3G1,CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 03期

关键词：

D O I：

10.1039/c39950000327

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The preparation from [Ru-3(CO)(11)(PPh(2)C=C-C drop C-R)] (R = Bu(t), Ph) Of the hexanuclear complexes [Ru-6(Co)(13)(mu-Co)(2)(mu-PPh(2))(mu(5)-C)(mu(3)-C-C drop CR)] (R = Bu(t) 1, Ph 2) containing a novel alkylidyne-carbide ligand is described; the structure of 1 is determined by a single-crystal X-ray diffraction study.

引用

页码：327 / 328

页数：2

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