CHARGE-TRANSFER COMPLEXES OF OCTAETHYLFERROCENE

被引：15

作者：

STEIN, D

SITZMANN, H

BOESE, R

机构：

[1] UNIV KAISERSLAUTERN,FACHBEREICH CHEM,ERWIN SCHRODINGER STR,W-6750 KAISERSLAUTERN,GERMANY

[2] UNIV ESSEN GESAMTHSCH,FACHBEREICH 8,W-4300 ESSEN 1,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 421卷 / 2-3期

关键词：

D O I：

10.1016/0022-328X(91)86412-J

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of octaethylferrocene (1) and 7,7',8,8'-tetracyano-p-chinodimethane (TCNQ) gives a 1:1 charge-transfer complex [(C5Et4H)2Fe]+[TCNQ]- (2a). The crystal structure of 2a has been determined at 110 K (a 8.967(l), b 9.074(l), c 10.997(2) angstrom, alpha-102.12(1), beta-102.04(1), gamma-98.64(1)-degrees, V 827.8(2) angstrom 3, Z = 1) and shown to consist of one-dimensional D+A-D+ ... - stacks. The reaction of 1 with 2,3,5,6-tetrafluoro-7,7',8,8'-tetracyano-p-chinodimethane (TCNQ-F4) gives a 1:1 charge-transfer complex with a dimeric anion, that crystallizes in the monoclinic space group P2(1)/c (a 15.193(3), b 16.303(2), c 15.157(7) angstrom, beta 115.84(2)-degrees, V 3379(l) angstrom 3, Z = 4, determined at 103 K). The known charge-transfer complex of decaethylferrocene with TCNQ has independently been subjected to a crystal structure analysis at 110 K.

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页码：275 / 283

页数：9

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