VISCOELASTIC PROPERTIES OF CHARGED COLLOIDS, POLYSTYRENE, AND SILICA-WATER SUSPENSIONS

被引:7
|
作者
MALLAMACE, F [1 ]
MICALI, N [1 ]
VASI, C [1 ]
机构
[1] CNR, IST TECN SPETTROSCOP, I-98166 MESSINA, ITALY
来源
PHYSICAL REVIEW A | 1990年 / 42卷 / 12期
关键词
D O I
10.1103/PhysRevA.42.7304
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
We report the shear viscosity measurements carried out in a dilute collidal solution of mono-disperse polystyrene particles as a function of the volume fraction of the dispersed phase and for different particles sizes in a completely deionized water suspension and in the presence of a small amount of salt (NaCl). The results are analyzed in the frame of a recent simple model, based on the theory of interaction between electrical double layers, that relates the rheological properties of the system to the interparticle potential. The comparison between the calculated high-frequency shear modulus and the viscosity data show better agreement. Therefore we can confirm the idea that in such systems the rheological behavior can be completely explained in terms of the interparticle potential energy of interaction.
引用
收藏
页码:7304 / 7311
页数:8
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