OPTICAL PATHLENGTH CONSIDERATIONS IN TRANSMISSION SPECTROELECTROCHEMICAL MEASUREMENTS

被引：18

作者：

SHU, FR ^{[1
]}

WILSON, GS ^{[1
]}

机构：

[1] UNIV ARIZONA, DEPT CHEM, TUCSON, AZ 85721 USA

来源：

ANALYTICAL CHEMISTRY | 1976年 / 48卷 / 12期

关键词：

D O I：

10.1021/ac50006a013

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A transmission spectroelectrochemical cell is described in which the optical path length can be varied to enable consideration of its effect on electrochemical characteristics such as cell time constant. The utility of the short path length cell was demonstrated in the measurement of the 2nd order homogeneous electron transfer rate constant for the reaction of horse heart cytochrome c and hexaammineuruthenium(II).

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页码：1676 / 1679

页数：4

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