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Catalytic activity of isoborneol-derived sulfides in asymmetric addition of diethylzinc to benzaldehyde
被引：0
作者：
Arai, Y
Nagata, N
Masaki, Y
机构：
关键词：
beta-hydroxysulfide;
diethylzinc;
catalyst;
chiral ligand;
(S)-1-phenylpropanol;
D O I：
暂无
中图分类号：
R914 [药物化学];
学科分类号：
100701 ;
摘要：
Enantioselective addition of diethylzinc to benzaldehyde in the presence of easily available, beta-hydroxysulfides 1 was investigated. The use of a catalytic amount of 1 gave (S)-1-phenylpropanol in excellent yield with high enantioselectivity, ranging from 85 to 88% ee.
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页码：2243 / 2245
页数：3
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