CATALYTIC-OXIDATION OF HYDROCARBONS AND ALCOHOLS BY CARBON-DIOXIDE ON OXIDE CATALYSTS

被引：69

作者：

KRYLOV, OV ^{[1
]}

MAMEDOV, AK ^{[1
]}

MIRZABEKOVA, SR ^{[1
]}

机构：

[1] AZERBAIJAN ACAD SCI,YU G MAMEDALIEV INST PETROCHEM PROC,BAKU 370604,AZERBAIJAN

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 1995年 / 34卷 / 02期

关键词：

D O I：

10.1021/ie00041a007

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Reactions of oxidative transformation of organic compounds of different classes (alkanes, alkenes, and alcohols) with a nontraditional oxidant, carbon dioxide, were studied on oxide catalysts Fe-O, Cr-O, Mn-O and on multicomponent systems based on manganese oxide. The supported manganese oxide catalysts are active, selective, and stable in conversion of the CH4 + CO2 mixture into synthesis gas and in oxidative dehydrogenation of C-2-C-7 hydrocarbons and the lower alcohols. Unlike metal catalysts manganese oxide based catalysts do not form a carbon layer during the reaction.

引用

页码：474 / 482

页数：9

共 34 条

[1] AIKA K, 1988, 9TH P INT C CAT CALG, V2, P907
[2] ARESTA M, 1986, NATO ASI SERIES C
[3] AN INSITU, ENERGY-DISPERSIVE X-RAY-DIFFRACTION STUDY OF NATURAL-GAS CONVERSION BY CO2 REFORMING
ASHCROFT, AT
CHEETHAM, AK
JONES, RH
NATARAJAN, S
THOMAS, JM
WALLER, D
CLARK, SM
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (13) : 3355 - 3358
[4] PARTIAL OXIDATION OF METHANE TO SYNTHESIS GAS-USING CARBON-DIOXIDE
ASHCROFT, AT
CHEETHAM, AK
GREEN, MLH
VERNON, PDF
[J]. NATURE, 1991, 352 (6332) : 225 - 226
[5] OXIDATIVE DEHYDROGENATION OF ETHANE OVER LANTHANA - ACTUAL NATURE OF THE ACTIVE PHASE
BERNAL, S
MARTIN, GA
MORAL, P
PERRICHON, V
[J]. CATALYSIS LETTERS, 1990, 6 (02) : 231 - 238
[6] BODROV IM, 1967, KINET KATAL, V8, P379
[7] REACTIONS OF CARBON-DIOXIDE WITH CARBON CARBON BOND FORMATION CATALYZED BY TRANSITION-METAL COMPLEXES
BRAUNSTEIN, P
MATT, D
NOBEL, D
[J]. CHEMICAL REVIEWS, 1988, 88 (05) : 747 - 764
[8] Breslow G.S., 1981, J CHEM SOC CHEM COMM, V21, P1145
[9] ACTIVATION OF CH4 AND ITS REACTION WITH CO2 OVER SUPPORTED RH CATALYSTS
ERDOHELYI, A
CSERENYI, J
SOLYMOSI, F
[J]. JOURNAL OF CATALYSIS, 1993, 141 (01) : 287 - 299
[10] BIFUNCTIONAL ACTIVATION OF CARBON-DIOXIDE - SYNTHESIS AND STRUCTURE OF A REVERSIBLE CO2 CARRIER
FACHINETTI, G
FLORIANI, C
ZANAZZI, PF
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (23) : 7405 - 7407

← 1 2 3 4 →