GALLOXANE AND ALUMOXANE HYDROXIDES - [GA(12)TBU(12)(MU(3)-O)(8)(MU-O)(2)(MU-OH)(4)] AND [AL(6)TBU(6)(MU(3)-O)(4)(MU-OH)(4)]

被引：0
作者：
LANDRY, CC
HARLAN, CJ
BOTT, SG
BARRON, AR
机构：
[1] HARVARD UNIV,DEPT CHEM,CAMBRIDGE,MA 02138
[2] UNIV N TEXAS,DEPT CHEM,DENTON,TX 76203
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 11期
关键词：
ALUMINUM COMPOUNDS; CAGE COMPOUNDS; COORDINATION; GALLIUM COMPOUNDS;
D O I：
10.1002/anie.199512011
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An unusual dodecagallium cage is isolated from the oxidation and hydrolysis of [tBu2Ga(Spy)]. The structure of 1 consists of a [tBuGa(μ‐X)GatBu]‐capped oxocube (X = O, OH). In addition 2 has been isolated. Both structures show crystallographic disorder of oxo and hydroxo ligands. H‐Spy = 2‐mercaptopyridine. (Formula Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany
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页码：1201 / 1202
页数：2
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