PHOSPHORAMIDATE MEDIATED CONVERSION OF TRICARBONYL(VINYLKETENE)IRON(O) COMPLEXES INTO TRICARBONYL(VINYLKETENIMINE)IRON(O) COMPLEXES

被引:12
作者
BENYUNES, SA [1 ]
GIBSON, SE [1 ]
STERN, JA [1 ]
机构
[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,LONDON SW7 2AY,ENGLAND
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1995年 / 11期
关键词
D O I
10.1039/p19950001333
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The anions of diethyl N-alkyl(aryl)phosphoramidates 1 react with tricarbonyl(vinylketene)iron(0) complexes 2 to give tricarbonyl(vinylketenimine) iron(0) complexes 3; the yield of 3 is dependent on the steric bulk of the phosphoramidate substituent R1 and the degree of substitution of the vinylketene complex substituent R2.
引用
收藏
页码:1333 / 1334
页数:2
相关论文
共 11 条
[1]  
Morris K.G., Saberi S.P., Slawin A.M.Z., Thomas S.E., Williams D.J., J. Chem. Soc., Chem. Commun., (1992)
[2]  
Morris K.G., Saberi S.P., Thomas S.E., J. Chem. Soc., Chem.Commun., (1993)
[3]  
Morris K.G., Saberi S.P., Salter M.M., Thomas S.E., Ward M.F., Slawin A.M.Z., Williams D.J., Tetrahedron, 49, (1993)
[4]  
Saberi S.P., Slawin A.M.Z., Thomas S.E., Williams D.J., Ward M.F., Worthington P.A., J. Chem. Soc., Chem. Commun., 2, (1994)
[5]  
Hill L., Richards C.J., Thomas S.E., J. Chem. Soc., Chem. Commun., (1990)
[6]  
Hill L., Saberi S.P., Slawin A.M.Z., Thomas S.E., Williams D.J., J. Chem. Soc., Chem. Commun., (1991)
[7]  
Saberi S.P., Thomas S.E., J. Chem. Soc., Perkin Trans., 1, (1992)
[8]  
Richards C.J., Thomas S.E., J. Chem. Soc., Chem. Commun., (1990)
[9]  
Alcock N.W., Richards C.J., Thomas S.E., Organometallics, 10, (1991)
[10]  
Wadsworth W.S., Emmons W.D., J. Org. Chem., 29, (1964)