STEREOSELECTIVE SYNTHESES OF RETRO-ISOMERS OF N-GLUCOASPARAGINE

被引：46

作者：

FREY, O ^{[1
]}

HOFFMANN, M ^{[1
]}

KESSLER, H ^{[1
]}

机构：

[1] TECH UNIV MUNICH,INST ORGAN CHEM & BIOCHEM,D-85747 GARCHING,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 18期

关键词：

C-GLYCOSIDES; GLYCOSYLATED AMINO ACIDS; HEPTONAMIDES;

D O I：

10.1002/anie.199520261

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new type of linkage between the anomeric center of a pyranose and an amino acid is represented by the C‐glycosidic amide bond (shown on the right). It was formed by coupling heptonic acids with a β‐aminoalanine derivative. Both the α and the β anomers were prepared selectively. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：2026 / 2028

页数：3

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