PALLADIUM-CATALYZED POLYENE CYCLIZATIONS - AN APPROACH TO THE PENTACYCLIC CARBON FRAMEWORK OF HALENAQUINONE AND XESTOQUINONE

被引:0
作者
CRISTOFOLI, WA [1 ]
KEAY, BA [1 ]
机构
[1] UNIV CALGARY,DEPT CHEM,CALGARY T2N 1N4,ALBERTA,CANADA
关键词
PALLADIUM; POLYENE CYCLIZATION; FURANS; HALENAQUINONE; XESTOQUINONE;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A seven step synthesis of the pentacyclic framework of xestoquinone and halenaquinone is described beginning with 3-(hydroxymethyl)furan and 3-bromo-2-naphthoyl chloride utilizing, as the ke step, a palladium catalyzed polyene cyclization.
引用
收藏
页码:625 / 627
页数:3
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