DETERMINATION OF 3-BOND H-1, H-1 COUPLING-CONSTANTS BETWEEN THE OLEFINIC PROTONS IN CYCLOALKENES BY MEANS OF H-1 CW OFF-RESONANCE C-13 NMR-SPECTROSCOPY

被引：8

作者：

RADEGLIA, R

POLESCHNER, H

HAUFE, G

机构：

[1] UNIV POTSDAM,KAI EV,PROJEKTGRP NATURSTOFFE,O-1532 KLEINMACHNOW,GERMANY

[2] UNIV MUNSTER,INST ORGAN CHEM,W-4400 MUNSTER,GERMANY

来源：

MAGNETIC RESONANCE IN CHEMISTRY | 1993年 / 31卷 / 07期

关键词：

OFF-RESONANCE; 2ND-ORDER EFFECTS; VICINAL H-1; H-1 COUPLING CONSTANTS; (E)/(Z) CONFIGURATION OF DOUBLE BONDS; CYCLOALKENES;

D O I：

10.1002/mrc.1260310706

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The H-1 CW off-resonance decoupled C-13 NMR spectra of (E)- and (Z)-cycloalkenes (C5-C-12) were measured. The higher order C-13 NMR multiplets obtained for the unsaturated carbons allow the determination of the vicinal H-1,H-1 coupling constant between the vinylic protons and thus the assignment of the configuration of the -CH2CH=CHCH2- fragment.

引用

页码：639 / 641

页数：3