DICHLOROKETENE-OLEFIN CYCLOADDUCTS IN SYNTHESIS - A SHORT, CONVENIENT, PROTOCOL FOR OLEFIN-]ALPHA-VINYLKETONE TRANSFORMATION

被引：9

作者：

MEHTA, G

ACHARYULU, PVR

机构：

[1] School of Chemistry, University of Hyderabad, Hyderabad

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 50期

关键词：

D O I：

10.1016/S0040-4039(00)61478-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple, preparatively useful sequence to alpha-vinylketones from olefins via their [2+2]-dichloroketene adducts is reported.

引用

页码：8157 / 8158

页数：2

共 10 条

[1]

BLUTHE N, 1984, TETRAHEDRON, V40, P3277, DOI 10.1016/0040-4020(84)85011-5

[2] MECHANISTIC CHANGE IN FAVORSKII REARRANGEMENT ON METHYL SUBSTITUTION [J].

BORDWELL, FG ;

CARLSON, MW ;

KNIPE, AC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (14) :3949-&

[3]

BRETSCH W, 1987, LIEBIGS ANN CHEM, P175

[4] NEW METHOD FOR PREPARING BETA-GAMMA-UNSATURATED KETONES - USE OF PHENYLSELENOACETALDEHYDE [J].

CLIVE, DLJ ;

RUSSELL, CG .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (09) :434-436

[5] A NEW 2-CARBON OLEFIN HOMOLOGATION PROCEDURE THAT LEADS TO ALPHA-CHLOROENONES - AN EFFICIENT SYNTHESIS OF D,L-MUSCONE [J].

DEPRES, JP ;

NAVARRO, B ;

GREENE, AE .

TETRAHEDRON, 1989, 45 (10) :2989-2998

[6] NOVEL FREE-RADICAL RING-FORMING REACTION OF DICHLOROCYCLOBUTANONES AND SEQUENTIAL RING EXPANSION [J].

DOWD, P ;

WEI, Z .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (25) :10084-10085

[7] TOTAL SYNTHESIS OF (+/-)-AFRICANOL AND (+/-)-ISOAFRICANOL [J].

FAN, WM ;

WHITE, JB .

JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (13) :3557-3562

[8]

FLETCHER VR, 1970, TETRAHEDRON LETT, P1071

[9] ULTRASOUND PROMOTED DICHLOROKETENE-OLEFIN CYCLO-ADDITIONS [J].

MEHTA, G ;

RAO, HSP .

SYNTHETIC COMMUNICATIONS, 1985, 15 (11) :991-1000

[10]

REISSIG HU, 1988, TOPICS CURRENT CHEM, V144

← 1 →