KINETICS OF CARBON DEPOSITION ON NICKEL METAL BY DECOMPOSITION OF CARBON-MONOXIDE

被引：4

作者：

SAKAI, N ^{[1
]}

CHIDA, T ^{[1
]}

TADAKI, T ^{[1
]}

SHIMOIIZAKA, J ^{[1
]}

机构：

[1] TOHOKU UNIV,DEPT CHEM ENGN,SENDAI,MIYAGI 980,JAPAN

来源：

JOURNAL OF CHEMICAL ENGINEERING OF JAPAN | 1985年 / 18卷 / 03期

关键词：

ADSORPTION - CARBON MONOXIDE - Decomposition - CHEMICAL REACTIONS - Reaction Kinetics - NICKEL AND ALLOYS;

D O I：

10.1252/jcej.18.199

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The kinetics of carbon deposition are reported for the temperature range 773-1023 K. A reaction model composed of adsorption and reaction steps is proposed and compared with experimental data. In this model the rate equation of carbon deposition takes into account the catalytic action of nickel. The calculated results are in good agreement with the experimental ones. The activation energy and the heat of adsorption of CO are 59. 3 kj/mol and 61. 7 kj/mol, respectively.

引用

页码：199 / 204

页数：6

共 13 条

[1] HYDROGENATION OF CATALYTIC CARBONS OBTAINED BY CO DISPROPORTIONATION OR CH4 DECOMPOSITION ON NICKEL [J].