MICROBIAL CONVERSION OF ALPHA-IONONE, ALPHA-METHYLIONONE, AND ALPHA-ISOMETHYLIONONE

被引：28

作者：

YAMAZAKI, Y ^{[1
]}

HAYASHI, Y ^{[1
]}

ARITA, M ^{[1
]}

HIEDA, T ^{[1
]}

MIKAMI, Y ^{[1
]}

机构：

[1] JAPAN TOBACCO INC,CENT RES INST,MIDORI KU,YOKOHAMA 227,JAPAN

来源：

APPLIED AND ENVIRONMENTAL MICROBIOLOGY | 1988年 / 54卷 / 10期

关键词：

Aspergillus - Gas chromatography - Liquid chromatography;

D O I：

10.1128/AEM.54.10.2354-2360.1988

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

α-Ionone, α-methylionone, and a-isomethylionone were converted by Aspergillus niger JTS 191. The individual bioconversion products from a-ionone were isolated and identified by spectrometry and organic synthesis. The major products were cis-3-hydroxy-a-ionone, trans-3-hydroxy-a-ionone, and 3-oxo-α-ionone. 2,3-Dehydro-α-ionone, 3,4-dehydro-β-ionone, and 1-(6,6-dimethyl-2-methylene-3-cyclohexenyl)-buten-3-one were also identified. Analogous bioconversion products from α-methylionone and α-isomethylionone were also identified. From results of gas-liquid chromatographic analysis during the fermentation, we propose a metabolic pathway for a-ionones and elucidation of stereochemical features of the bioconversion. © 1988, American Society for Microbiology.

引用

页码：2354 / 2360

页数：7