A TRIOSMIUM CLUSTER COMPLEX WITH A CARBENE LIGAND IN AN UNUSUAL COORDINATION MODE

被引：18

作者：

EDWARDS, AJ ^{[1
]}

GALLOP, MA ^{[1
]}

JOHNSON, BFG ^{[1
]}

KOHLER, JU ^{[1
]}

LEWIS, J ^{[1
]}

RAITHBY, PR ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 10期

关键词：

D O I：

10.1002/anie.199410931

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The face‐capping carbene ligand displays a chairlike conformation and unusual side‐on bonding in the triosmium cluster 1. This air‐stable compound reacts in the presence of Lewis bases with atmospheric oxygen to form 2, in which the cyclohexadienone ligand is coordinated in a new mode to the Os3 framework. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

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页码：1093 / 1094

页数：2

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