PROTON CONDUCTION IN CA-SUBSTITUTED AND SR-SUBSTITUTED LAPO4

被引：161

作者：

NORBY, T ^{[1
]}

CHRISTIANSEN, N ^{[1
]}

机构：

[1] HALDOR TOPSOE RES LABS,DK-2800 LYNGBY,DENMARK

来源：

SOLID STATE IONICS | 1995年 / 77卷

关键词：

PROTON CONDUCTION; LAPO4; CA; AND SR-SUBSTITUTED;

D O I：

10.1016/0167-2738(94)00274-V

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

LaPO4 with nominally 5 atom% Ca or Sr was synthesised using co-precipitation, cold-pressed to bars, and sintered at 1300 degrees C. The electrical conductivity in wet air was mainly protonic up to approximately 900 degrees C; it increased with increasing humidity and decreased when protons were replaced by deuterons in situ by equilibrating the samples in air containing D2O. Above 900 degrees C the proton conductivity fell and a native conductivity contribution became dominant.

引用

页码：240 / 243

页数：4

共 8 条

[1]

Alberti G, 1992, PROTON CONDUCTORS SO, P238

[2]

Colomban Ph., 1992, PROTON CONDUCTORS, P254

[3] HUMIDITY SENSOR WITH SINTERED BETA-CA(PO3)2 FOR HIGH-TEMPERATURE USE [J].