QUADRATIC HYPERPOLARIZABILITIES OF GROUP-6A METAL-CARBONYL-COMPLEXES

被引:61
作者
CHENG, LT
TAM, W
EATON, DF
机构
[1] Central Research and Development Department, Experimental Station, E. I. du Pont de Nemours & Co., Wilmington, Delaware 19880-0356
关键词
D O I
10.1021/om00161a003
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The molecular hyperpolarizabilities of M-(CO)5(pyridine), M(CO)4(1,10-phenanthroline), and M-(CO)5(styrylpyridine) complexes (M = Cr, Mo, W) have been measured. The relationships between molecular hyperpolarizabilities and molecular modifications on the structures are discussed. © 1990, American Chemical Society. All rights reserved.
引用
收藏
页码:2856 / 2857
页数:2
相关论文
共 17 条
[11]   ORGANOMETALLIC HETEROCYCLIC CHEMISTRY .2. SPECTRAL AND ELECTROCHEMICAL PROPERTIES OF PYRIDAZINE, PYRAZINE, AND PYRIMIDINE COMPLEXES OF TUNGSTEN PENTACARBONYL [J].
PANNELL, KH ;
GUADALUPEDELAPAZSAENZGON.M ;
LEANO, H ;
IGLESIAS, R .
INORGANIC CHEMISTRY, 1978, 17 (04) :1093-1095
[12]  
Tam W., 1988, Proceedings of the SPIE - The International Society for Optical Engineering, V971, P107, DOI 10.1117/12.948221
[13]   OXIDATIVE ADDITION OF PD(0) AND PT(0) WITH AROMATIC HALIDES - MATERIAL FOR 2ND-HARMONIC GENERATION [J].
TAM, W ;
CALABRESE, JC .
CHEMICAL PHYSICS LETTERS, 1988, 144 (01) :79-82
[14]   Channel Inclusion Complexation of Organometallics: Dipolar Alignment for Second Harmonic Generation [J].
Tam, Wilson ;
Eaton, David F. ;
Calabrese, Joseph C. ;
Williams, Ian D. ;
Wang, Ying ;
Anderson, Albert G. .
CHEMISTRY OF MATERIALS, 1989, 1 (01) :128-140
[15]  
WRIGHTON M, 1973, MOL PHOTOCHEM, V5, P179
[16]   PHOTOSUBSTITUTION REACTIVITY OF A SERIES OF PENTACARBONYLPYRIDINOTUNGSTEN(O) COMPLEXES HAVING LIGAND-FIELD OR CHARGE-TRANSFER LOWEST EXCITED-STATES [J].
WRIGHTON, MS ;
ABRAHAMSON, HB ;
MORSE, DL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (14) :4105-4109
[17]   NATURE OF LOWEST EXCITED-STATE AND PHOTOSUBSTITUTION REACTIVITY OF TETRACARBONYL-1,10-PHENANTHROLINETUNGSTEN(0) AND RELATED COMPLEXES [J].
WRIGHTON, MS ;
MORSE, DL .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 97 (03) :405-419