Unexpected reactions of anionic intermediates [(mu-RS)(mu-Se)Fe-2(CO)(6)](-) with SO2Cl2. Synthesis of [(mu-RS)Fe-2(CO)(6)](2)(mu(4)-Se)(R=Ph, Et, Pr-n, (t)Bu) and crystal structure of [(mu PhS)Fe-2(CO)(6)](2)(mu(4)-Se)

被引：14

作者：

Song, LC ^{[1
]}

Yan, CG ^{[1
]}

Hu, QM ^{[1
]}

Huang, XY ^{[1
]}

机构：

[1] CHINESE ACAD SCI,FUJIAN INST RES STRUCT MATTER,STATE KEY LAB STRUCT CHEM,FUJIAN 350002,PEOPLES R CHINA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 505卷 / 01期

关键词：

selenium; iron; CO-bridged anion; sulfuryl chloride; X-ray structure; cluster;

D O I：

10.1016/0022-328X(95)05575-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The addition of elemental selenium to CO-bridged anions [(mu-RS)(mu-CO)Fe-2(CO)(6)](-) gave new selenido-bridged intermediates [(mu-RS)(mu-Se)Fe-2(CO)(6)](-). Treatment of the intermediates in situ with SO2Cl2, afforded unexpected products [(mu-RS)Fe-2(CO)(6)](2)(mu(4)-Se)(R = Ph, Et, Pr-n, (t)Bu), among which the structure of the product with R = Ph was confirmed by X-ray crystallography. It crystallized in the monoclinic space group P21/n(#14) with the lattice constants a = 8.971(3), b = 12.891(8), c = 26.955(7) Angstrom, beta = 98.03(2)* and Z = 4. The structure was refined to an R value of 0.069.

引用

页码：119 / 121

页数：3

共 50 条

[1] REACTIONS OF (MU(2)-CARBYNE)(MU-RS)FE-2(CO)(6) COMPLEXES - ISOMERIZATION AND ACETYLENE INSERTION
SEYFERTH, D
RUSCHKE, DP
DAVIS, WM
ORGANOMETALLICS, 1994, 13 (12) : 4695 - 4703
[2] SYNTHESIS AND CHARACTERIZATION OF PHTHALOYL BRIDGED IRON-SULFUR COMPLEXES [(MU-RS)FE-2(CO)(6)](2)(MU-OCC6H4CO-MU)
SONG, LC
HU, QM
SU, ZY
CAO, XC
ZHU, J
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 1995, 16 (06): : 905 - 908
[3] Formation of (mu-RE)(mu-S-)Fe-2(CO)(6) and (mu-RE)(mu-Se-)Fe-2(CO)(6) (E=S, Se) anions and a comparative study of their reactions with SO2Cl2, ClC(O)ZC(O)Cl (Z=(CH2)(2), C6H4), or p-MeC(6)H(4)SO(2)Cl. Single-crystal structures of [(mu-EtS)Fe-2(CO)(6)](2)(mu(4)-Se) and (mu-EtS)(mu-p-MeC(6)H(4)SO(2))Fe-2(CO)(6)
Song, LC
Yan, CG
Hu, QM
Wang, RJ
Mak, TCW
Huang, XY
ORGANOMETALLICS, 1996, 15 (06) : 1535 - 1544
[4] Unexpected reactions of anionic intermediates [(mu-RE)(mu-S=CS)Fe-2(Co)(6)](-) with SO2Cl2. Synthesis and characterization of novel dithioformato-bridged double clusters [(mu-RE)Fe-2(CO)(6)](2)(mu-S=CS-mu) (E=S,Se)
Song, LC
Yan, CG
Hu, QM
Wu, BM
Mak, TCW
ORGANOMETALLICS, 1997, 16 (04) : 632 - 635
[5] Formation of novel tellurium-containing anions [(mu-RTe)(mu-CO)Fe-2(CO)(6)(-)] and synthesis of Fe/Te clusters (mu-RTe)(mu-sigma,pi-PhC=CH2)Fe-2(CO)(6), (mu-RTe)Fe-2(CO)(6), and [(mu-RTe)Fe-2(CO)(6)](2)(mu-Te-Te-mu). X-ray crystal structure of [(mu-PhTe)Fe-2(CO)(6)](2)(mu-Te-Te-mu)
Song, LC
Yan, CG
Hu, QM
Huang, XY
ORGANOMETALLICS, 1997, 16 (17) : 3769 - 3774
[6] ACETYLENIC DERIVATIVES OF FE-2(CO)(6)(MU-SE-2) - SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF [(CO)(6)FE-2(MU-SEC(H)=C(H)SE)] AND [((CO)(6)FE2SE2)(2)(MU-C(H)-C(H))]
MATHUR, P
DASH, AK
HOSSAIN, MM
SATYANARAYANA, CVV
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 493 (1-2) : 257 - 260
[7] FORMATION OF ASYMMETRICAL TWIN CLUSTERS [(MU-RS)FE2(CO)6](MU-4-S)[(MU-R'S)FE2(CO)6] BY REACTION OF (MU-RS)(MU-XMGS)FE2(CO)6 WITH (MU-R'S)[MU-PHC(O)S]-FE2(CO)6 - CRYSTAL-STRUCTURE OF [(MU-ETS)FE2(CO)6]-(MU-4-S)[MU-PHS)FE2(CO)6]
SONG, LC
HU, QM
ZHANG, LY
WANG, H
ZHOU, ZY
LIU, L
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 412 (1-2) : C19 - C22
[8] Synthesis, spectroscopic and structural characterisation of {(CO)(3)Fe(mu-CH2)Se}(2) and (CO)(6)Fe-2{mu-Se(CH2)(n)Se} (n=1,2)
Mathur, P
Manimaran, B
Trivedi, R
Hossain, MM
Arabatti, M
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 515 (1-2) : 155 - 162
[9] REACTIONS OF [FE-2(CO)(6)(MU-CO)(MU-DPPM)], WITH PHC-CH AND THE PHOSPHA-ALKYNE, (T)BUC-P - CRYSTAL AND MOLECULAR-STRUCTURES OF THE 4 DIIRON COMPLEXES [FE-2(CO)(4)(MU-CO)(MU-DPPM)(2)], [FE-2(CO)(5)(MU-DPPM)(MU-ETA(2)-CHC(CO)PH], [FE-2(CO)(4)(MU-CO)(MU-DPPM)(MU-ETA(2)-(T)BUCP)], AND [FE-2(CO)(5)(MU-DPPM)(MU-ETA(2)-PC(CO)(T)BU)]
HITCHCOCK, PB
MADDEN, TJ
NIXON, JF
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 463 (1-2) : 155 - 162
[10] ADDITION OF PHENYLACETYLENE TO THE MIXED-CHALCOGENIDE COMPOUNDS (CO)(6)FE-2(MU-SETE), (CO)(6)FE-2(MU-SSE), AND (CO)(6)FE-2(MU-STE) - STRUCTURAL CHARACTERIZATION OF (CO)(6)FE-2(MU-SEC(H)=C(PH)TE)
MATHUR, P
HOSSAIN, MM
UMBARKAR, S
SATYANARAYANA, CVV
TAVALE, SS
PURANIK, VG
ORGANOMETALLICS, 1995, 14 (02) : 959 - 963

← 1 2 3 4 5 →