ENANTIOSELECTIVE HYDROLYSIS OF CYCLOPENTANEACETIC ACID-ESTERS RELATED TO METHYL JASMONATE

被引：0

作者：

KERRY, S ^{[1
]}

DART, RK ^{[1
]}

MARPLES, BA ^{[1
]}

机构：

[1] UNIV TECHNOL,DEPT CHEM,LOUGHBOROUGH LE11 3SP,LEICS,ENGLAND

来源：

ENZYME AND MICROBIAL TECHNOLOGY | 1993年 / 15卷 / 10期

关键词：

ENANTIOSELECTIVE HYDROLYSIS; CYCLOPENTANEACETIC ACID ESTERS; METHYL JASMONATE; ASPERGILLUS-NIGER; ASPERGILLUS-CARBONARIUS;

D O I：

10.1016/0141-0229(93)90092-G

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

The hydrolysis of methyl jasmonate with Aspergillus niger and A. carbonarius is shown to be very dependent upon the particular structure of the substrate. Some variation of the side chain at C-2 is tolerated, whereas the 3-keto group and the methyl ester moieties are particularly important. Porcine pancreatic lipase, Candida lipase, and Rhizopus lipase are unreactive towards butyl jasmonate.

引用

页码：818 / 820

页数：3

共 18 条

[1]

BULLIVANT MJ, 1976, PYRETHRUM POST, V13, P100

[2] ENANTIOSELECTIVE HYDROLYSIS OF RACEMIC METHYL JASMONATE USING MICROORGANISMS AND ISOLATED-ENZYMES [J].

DART, RK ;

KERRY, S ;

MARPLES, BA .

ENZYME AND MICROBIAL TECHNOLOGY, 1992, 14 (12) :954-958

[3] SYNTHESES DU D,L-JASMONATE DE METHYLE (CIS-PENTENE-2'-Y1-2-OXO-3-CYCLOPENTYLACETATE DE METHYLE) ET DE DEUX ISOMERES [J].

DEMOLE, E ;

STOLL, M .

HELVETICA CHIMICA ACTA, 1962, 45 (02) :692-&

[4] ABSOLUTE CONFIGURATION OF METHYL JASMONATE [J].

HILL, RK ;

EDWARDS, AG .

TETRAHEDRON, 1965, 21 (06) :1501-&

[5]

HO TL, 1982, CHEM IND-LONDON, P721

[6] SELECTIVE DEOXYGENATION OF KETONES AND ALDEHYDES INCLUDING HINDERED SYSTEMS WITH SODIUM CYANOBOROHYDRIDE [J].

HUTCHINS, RO ;

MILEWSKI, CA ;

MARYANOF.BE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (11) :3662-3668

[7] SYNTHESIS IN JASMONE SERIES .7. PREPARATION OF 2-ALKYLCYCLOPENTENONES AND 2-ALKYLCYCLOPENTANONES [J].

KATSIN, N ;

IKAN, R .

SYNTHETIC COMMUNICATIONS, 1977, 7 (03) :185-188

[8]

MATSUI M, 1986, JPN KOKAI TOKKYO KOH, V61, P17

[9]

MATSUI M, 1986, JPN KOKAI TOKKYO KOH, V61, P531

[10] THE BAEYER-VILLIGER OXIDATION OF BICYCLIC KETONES [J].

MEINWALD, J ;

FRAUENGLASS, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (19) :5235-5239

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