OXO-OSMIUM(VI), NITRIDO-OSMIUM(VI) AND IMIDO-OSMIUM(VI) COMPLEXES WITH A STERICALLY BULKY CHELATING ALKOXIDE LIGAND

被引：22
|
作者：
LI, ZY
YU, WY
CHE, CM
POON, CK
WANG, RJ
MAK, TCW
机构：
[1] UNIV HONG KONG,DEPT CHEM,POKFULAM RD,HONG KONG,HONG KONG
[2] CHINESE UNIV HONG KONG,DEPT CHEM,SHA TIN,HONG KONG
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 10期
关键词：
D O I：
10.1039/dt9920001657
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis and characterization of dioxoosmium(VI) complexes cis-[OsO2L] and trans-[OsO2L'] (L' = NH2But, pyridine or 4-tert-butylpyridine), the nitrido complex [OsN(L)Cl], and imido complexes [OsL(NCOCF3)Cl(O2CCF3)] and [OsL(NPh)2] [H2L = 2,6-bis(2-hydroxy-2,2-diphenylethyl)pyridine] are described. The crystal structures of [OsN(L)Cl] and [OsO2L(NH2But)].0.5C6H14 have been determined: the Os=N and average Os=O bond distances are 1.634(5) and 1.741(5) angstrom, respectively.
引用
收藏
页码：1657 / 1661
页数：5
相关论文
共 50 条
  • [1] SYNTHESIS OF MIXED-LIGAND COMPLEXES WITH NITRIDO-OSMIUM(VI) AND NITRIDO-OSMIUM (VIII)
    TA, N
    PRAMANIK, P
    SEN, D
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1974, 51 (02) : 374 - 374
  • [2] HYDROXYCARBOXYLATO OXO-OSMIUM(VI) COMPLEXES
    EDWARDS, CF
    GRIFFITH, WP
    POLYHEDRON, 1991, 10 (01) : 61 - 65
  • [3] SYNTHESIS AND CHARACTERIZATION OF OXO-OSMIUM(VI) ALKOXIDE AND ALKYL COMPLEXES
    MARSHMAN, RW
    SHAPLEY, PA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1987, 194 : 264 - INOR
  • [4] OXO-OSMIUM(VI)-PYRIDINE COMPLEXES OF NUCLEOSIDES
    DANIEL, FB
    BEHRMAN, EJ
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1973, (AUG26): : 26 - 26
  • [5] OXO-OSMIUM(VI)-LIGAND COMPLEXES OF ISOPENTENYL ADENINE AND ISOPENTENYL ADENOSINE
    RAGAZZO, JA
    BEHRMAN, EJ
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1975, 170 (AUG24): : 121 - 121
  • [6] REACTIVITY STUDIES OF NEW NITRIDO AND IMIDO COMPLEXES OF OSMIUM(VI)
    SHUSTA, JM
    MARSHMAN, RW
    SHAPLEY, PA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1991, 202 : 219 - ORGN
  • [7] NON-EXCHANGING OXO-OSMIUM (VI) LIGAND COMPLEXES OF NUCLEOSIDES
    DANIEL, FB
    BEHRMAN, EJ
    FEDERATION PROCEEDINGS, 1974, 33 (05) : 1538 - 1538
  • [8] REACTION OF OXO-OSMIUM(VI)-PYRIDINE COMPLEXES WITH THYMINE GLYCOLS
    SUBBARAMAN, LR
    SUBBARAMAN, J
    BEHRMAN, EJ
    JOURNAL OF ORGANIC CHEMISTRY, 1973, 38 (08): : 1499 - 1504
  • [9] Crystallographic and Theoretical Study of Osme Bonds in Nitrido-Osmium(VI) Complexes
    Gomila, Rosa M.
    Frontera, Antonio
    INORGANICS, 2022, 10 (09)
  • [10] TRANS-ESTERIFICATION OF OXO-OSMIUM(VI) LIGAND COMPLEXES OF THYMINE DERIVATIVES
    MIDDEN, WR
    CHANG, CH
    CLARK, RL
    BEHRMAN, EJ
    JOURNAL OF INORGANIC BIOCHEMISTRY, 1980, 12 (02) : 93 - 105
12345