COMPARISON OF THE DYNAMIC PROPERTIES OF SOLID POLYURETHANE ELASTOMERS

被引:13
作者
KOGELNIK, HJ
HUANG, HH
BARNES, M
MEICHSNER, R
机构
[1] Polyurethane Division, Mobay Corporation, Pittsburgh, PA 15205, Mobay Road
[2] Bayer AG, D5090 Leverkusen
关键词
D O I
10.1177/009524439102300405
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Standard elastomeric formulations are based on three components: a) diisocyanates such as TDI, MDI and NDI b) polyols with an ester, ether, and/or carbonate backbone c) chain extenders that are reactive glycols or aromatic diamines Such standard formulations were subjected to dynamic tests to determine their relative load bearing capacities (constant load testing methods were generally used). These results could be correlated to a certain extent with routinely measured mechanical properties. The behavior of materials chain extended with aromatic diamines (polyurea urethanes) was somewhat different from the glycol-extended systems. The polyurea urethanes have a high softening temperature, show little thermoplasticity and a relatively high set after testing. Glycol-extended systems showed relatively little set after deformation, but the softening temperature of such elastomers are relatively low. Although the investigated system could be manufactured in a wide hardness range, the optimal dynamic properties were usually found only in a very narrow hardness range. The optimal results were obtained with NDI as diisocyanate and 1,4-butanediol as extender.
引用
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页码:314 / 344
页数:31
相关论文
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