SELF-ASSEMBLED MONOLAYERS CONTAINING POLYDIACETYLENES

被引：159

作者：

BATCHELDER, DN

EVANS, SD

FREEMAN, TL

HAUSSLING, L

RINGSDORF, H

WOLF, H

机构：

[1] UNIV LEEDS,DEPT PHYS,LEEDS LS2 9JT,ENGLAND

[2] UNIV MAINZ,DEPT ORGAN CHEM,MAINZ,GERMANY

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1994年 / 116卷 / 03期

关键词：

D O I：

10.1021/ja00082a028

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The formation of self-assembled dialkyl disulfide-functionalized monolayers containing diacetylenes is reported for the first time. The diacetylene derivative used was [S(CH2)(2)COO(CH2)(9)C drop CC drop C(CH2)(13)CH3](2) and was seen to form well-ordered monolayers when adsorbed on gold from THF. The monomer was readily converted to the polymeric form by a short exposure to UV radiation. A ''blue'' polymer was formed which was stable against further irradiation; that is, it did not become ''red''. During the polymerization the alkyl side chains displayed some reorganization.

引用

页码：1050 / 1053

页数：4

共 23 条

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[2]

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