CONVERSION OF BENZAL CHLORIDE TO STILBENE BY ELECTROGENERATED COBALT(I)(SALEN) A DOUBLY ELECTROCATALYTIC PROCESS

被引：20

作者：

FRY, AJ

SIRISOMA, UN

LEE, AS

机构：

[1] Hall-Atwater Laboratory of Chemistry, Wesleyan University, Middletown

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 05期

关键词：

D O I：

10.1016/0040-4039(93)89018-L

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Benzal chloride is converted to a mixture consisting primarily of cis- and trans-stilbene by the action of electrochemically-generated cobalt(I)(salen). The process involves a sequence involving electrocatalytic conversion of benzal chloride to a mixture of meso- and dl-1,2-dichloro- 1,2-diphenylethane, followed by electrocatalyzed conversion of the latter to the stilbenes. Each of the diastereomeric dichlorides affords the same mixture of stilbenes under the reaction conditions.

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页码：809 / 812

页数：4

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