NON-METALLOCATALYZED EPOXIDATION OF CHIRAL UNSATURATED LACTAMS BY TERTIARY AMINE N-OXIDES

被引：17

作者：

ANDRES, CJ ^{[1
]}

SPETSERIS, N ^{[1
]}

NORTON, JR ^{[1
]}

MEYERS, AI ^{[1
]}

机构：

[1] COLORADO STATE UNIV,DEPT CHEM,FT COLLINS,CO 80523

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 10期

基金：

美国国家卫生研究院; 美国国家科学基金会;

关键词：

D O I：

10.1016/0040-4039(95)00114-R

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Tertiary amine N-oxides were used to stereospecifically epoxidize chiral unsaturated bicyclic lactams in high yields (90-99%) at room temperature. This appears to be the first reported example of tertiary amine N-oxides acting as epoxidizing agents in the absence of a metal catalyst.

引用

页码：1613 / 1616

页数：4

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