SELECTIVE CONVERSION OF NITROBENZENE TO PHENYLCARBAMATES CATALYZED BY PD(II) AND HETEROPOLYACIDS

被引：12
作者：
LEE, JS
WOO, JW
LEE, CW
HONG, KS
YEO, JK
机构：
[1] Department of Chemical Engineering, Pohang Institute of Science and Technology, Pohang
[2] Lucky Central Research Institute, Daejeon, Science Town
来源：
KOREAN JOURNAL OF CHEMICAL ENGINEERING | 1990年 / 7卷 / 02期
关键词：
D O I：
10.1007/BF02705060
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A homogeneous catalyst system of Pd(ll) and a heteropolyacid (HPA) converts nitrobenzene to N-phenylcarbamate with a selectivity of 96.3% at 100% nitrobenzene conversion, which appears to be the best value known in the literature. However, the catalyst forms solid deposits during the reaction. © 1990 Korean Institute of Chemical Engineering.
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页码：145 / 147
页数：3
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