REDOX CHEMISTRY OF RU(OEP)(CH3)2 - ISOLATION OF THE BRIDGING METHYLENE COMPLEX RU(OEP-N-MU-CH2-)(CH3)+

被引：18

作者：

SEYLER, JW ^{[1
]}

SAFFORD, LK ^{[1
]}

FANWICK, PE ^{[1
]}

LEIDNER, CR ^{[1
]}

机构：

[1] PURDUE UNIV,DEPT CHEM,W LAFAYETTE,IN 47907

来源：

INORGANIC CHEMISTRY | 1992年 / 31卷 / 09期

关键词：

D O I：

10.1021/ic00035a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first example of a porphyrin complex with a bridging CH2, Ru(OEP-N-mu-CH2-)(CH3)+, has been isolated as part of a study of the redox-induced reactions of Ru(OEP)(CH3)2 (OEP = octaethylporphyrin dianion). The methylene-bridged complex is formed by H. abstraction from the Ru(OEP-N-CH3)(CH3)+ complex.

引用

页码：1545 / 1547

页数：3

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